{
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    "title": "Porewater methane concentrations and d13C-CH4 values in Alvin pushcore samples from Guaymas Basin hydrothermal sediments collected on R\/V Atlantis cruise AT37-06 in December 2016 (NCEI Accession 0278708)",
    "description": "This dataset contains chemical data collected on Alvin and R\/V Atlantis during cruise AT37-06 and deployment AT37-06_Alvin_Dives in the Gulf of California from 2016-12-09 to 2016-12-27. These data include depth and methane. The instruments used to collect these data include Flame Ionization Detector, Gas Chromatograph, Isotope-ratio Mass Spectrometer, and Push Corer. These data were collected by Samantha B. Joye of University of Georgia and Andreas Teske of University of North Carolina at Chapel Hill as part of the \"Collaborative Research: Microbial Carbon cycling and its interactions with Sulfur and Nitrogen transformations in Guaymas Basin hydrothermal sediments (Guaymas Basin Interactions)\" project. The Biological and Chemical Oceanography Data Management Office (BCO-DMO) submitted these data to NCEI on 2021-03-12.\n\nThe following is the text of the dataset description provided by BCO-DMO:\n\nGuaymas porewater methane\n\nDataset Description:\nAcquisition Description:\nMethodology: Porewater Methane concentrations were determined by headspace Gas Chromatography - flame ionization detection, and d13C signatures of methane were determined by Gas Chromatography coupled to Mass Spectrometry, using a Finnigan MAT Delta S isotope ratio Mass Spectrometer inlet system.\n\nSampling and Analytical Procedures: For combined concentration and \u03b4 13 C analysis of methane, 2 ml sediment subsamples were added to 30 ml serum vials containing 2 ml of 1 M sodium hydroxide solution, sealed with thick butyl rubber stoppers, crimped with aluminum seals and stored at 4\u00b0C. Due to shipping problems and a resulting shortage of serum vials, only selected sediment cores were sampled for methane. Since cores were retrieved unpressurized, outgassing may have impacted in particular the measurements of methane concentrations near and above saturation, 1.5 mM. After the cruise, the methane samples were analyzed by headspace gas chromatography-flame ionization detection (GC-FID) at Florida State University (Magen et al., 2014). Gas samples were analyzed for \u03b4 13 C by injecting 0.1 to 0.5 ml of sample into a gas chromatograph interfaced to a Finnigan MAT Delta S isotope ratio Mass Spectrometer inlet system as previously described (Chanton and Liptay 2000). Values are reported in the per mil (\u2030) notation relative to Vienna Pee Dee Belemnite (VPDB). Sampling site names are based on Teske et al. 2016 and Teske et al. 2021.\n\nKnown Problems\/Issues : Problems with Mexican customs and the agent used by WHOI at the time have resulted in limited availability of sampling gear and sampling vials on the ship. Transport problems during the return trip have caused sample losses among the porewater samples, which are evident in occasional gaps in porewater profiles or short profiles.",
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    "bureauCode": [
        "010:04"
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    "modified": "2023-05-25T06:12:44.542Z",
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    "keyword": [
        "0278708",
        "DEPTH - OBSERVATION",
        "Methane (CH4)",
        "chromatograph",
        "corer",
        "flame ionization detector",
        "mass spectrometer",
        "chemical",
        "DSV Alvin",
        "R\/V Atlantis",
        "University of Georgia",
        "University of North Carolina - Chapel Hill",
        "Biological and Chemical Oceanography Data Management Office",
        "Gulf of California",
        "oceanography",
        "BCO-DMO > Biological and Chemical Oceanography Data Management Office",
        "Collaborative Research: Microbial Carbon cycling and its interactions with Sulfur and Nitrogen transformations in Guaymas Basin hydrothermal sediments (Guaymas Basin Interactions)",
        "AT37-06",
        "AT37-06_Alvin_Dives",
        "Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1357238",
        "Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1357360",
        "depth",
        "depth core",
        "latitude",
        "longitude",
        "methane",
        "site",
        "EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY",
        "Conc_CH4_mM",
        "Conc_CH4_pcnt",
        "Conc_CH4_ppm",
        "Depth",
        "Depth_Dive",
        "Lat",
        "Lon",
        "Site",
        "Site_Name",
        "del_CH4",
        "del_CH4_Std_Dev",
        "Flame Ionization Detector",
        "Gas Chromatograph",
        "Isotope-ratio Mass Spectrometer",
        "Push Corer",
        "FLAME-IONIZATION DETECTOR > FLAME-IONIZATION DETECTOR",
        "GAS CHROMATOGRAPHS > GAS CHROMATOGRAPHS",
        "MASS SPECTROMETERS > MASS SPECTROMETERS",
        "Alvin pushcore",
        "Finnigan MAT Delta S isotope ratio Mass Spectrometer",
        "unknown (Flame Ionization Detector)",
        "unknown (Gas Chromatograph)",
        "Alvin",
        "R\/V Atlantis",
        "SUBMARINE",
        "Ships",
        "ALVIN (ICES code: 31A5)",
        "ATLANTIS (ICES code: 33AT)",
        "OCEAN > PACIFIC OCEAN > NORTH PACIFIC OCEAN",
        "Guaymas Basin",
        "environment",
        "oceans"
    ]
}